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MSMA - Identification, toxicity, use, water pollution potential, ecological toxicity and regulatory information |
Note: See Working with the Information on this Page section below for important notes about this data. |
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| Identifying information, including synonyms, ID numbers, use type, chemical classification, a link to a list of all products containing this chemical and a list of the top crops this pesticide is used on in California. | |
| Signs and symptoms of poisoning, first aid, and links to treatment information for this chemical. | |
| Link to information on toxicity to humans, including carcinogenicity, reproductive and developmental toxicity, neurotoxicity, and acute toxicity. | |
| Links to world-wide registration status as well as regulatory information for the U.S. and California. | |
| Water quality standards and physical properties affecting water contamination potential. | |
| Toxicity to aquatic organisms. | |
| List of chemicals in the same family, including breakdown products, salts, esters, isomers, and other derivatives. | |
Chemical Identification and Use for MSMA |
Basic Identification Information About This Chemical |
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| Chemical Name: | MSMA |
| CAS Number: | 2163-80-6 |
| U.S. EPA PC Code: |
013803 (Same as US EPA PC Code 613803)
613803 (Same as US EPA PC Code 013803) |
| CA DPR Chem Code: | 34 |
| Molecular Weight: | 161.96 |
| Molecular Structure: | ![]() |
| Use Type: |
Defoliant
,
Herbicide
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| Chem Class: |
Heavy metal
,
Organoarsenic
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View Related Chemicals |
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Additional Resources About This Chemical Class and Use Type | |
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See the Global Pesticide Resources page for many additional links. |
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Historical Use of this ChemicalTop five crops and sites for this pesticide in California | |
Landscape
Cotton
Ornamental Turf
Almonds
Oranges
View All Crops and Sites | |
Other Names for this Chemical | |
| 00034 (CA DPR Chem Code Text) , 00034 (CA DPR Chem Code) , 013803 (US EPA PC Code Text) , 13803 (US EPA PC Code) , 2163-80-6 (CAS number) , 2163806 , 2163806 (CAS number without hyphens) , 34 (CA DPR Chem Code) , 34 (CA DPR Chem Code) , 613803 (US EPA PC Code Text) , 613803 (US EPA PC Code) , Ansar 170 , Ansar 529 , Arsanote Liquid , Arsenic as elemental, present as monosodium methane arsonate , Arsonic acid, methyl-, monosodium salt , Bueno , Dal-E-Rad , Deconate , Mesamate , methanearsonic acid sodium salt , Methanearsonic acid, monosodium salt , Methylarsonic acid, monosodium salt , Monate Merge 823 , Monosodium acid methanearsonate , Monosodium methane arsenate , Monosodium Methanearsonate , Monosodium methylarsonate , MSMA , MSMA , MSMA (and salts) , MSMA Monosodium methaearsonate , Phyban H.C. , Silvisar 550 , sodium hydrogen methylarsonate , Sodium methane arsonate (SMA) , Target MSMA , Weed - Broom (use 3 code nos. 012301, 013803 and 030001) mixt, (DSMA, Bromacil & 2,4-D) , Weed - Broom (use 3 EPA PC code nos. 012301, 013803 and 030001) mixt, (DSMA, Bromacil & 2,4-D) , Weed-S-Rad | |
Products Containing This ChemicalCurrent and historic U.S. registered products | |
Signs and Symptoms of MSMA Poisoning |
NOTE! There may be other diseases and chemicals that have similar symptoms. |
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If you have a poisoning emergency in the United States call 1-800-222-1222. |
MSMA is a Arsenical compound. |
Symptoms of Poisoning with Arsenical Compounds |
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- Garlic odor of breath and feces, metallic taste in mouth. |
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Source for Group Symptoms: Recognition and Management of Pesticide Poisoning, 5th edition, U.S. EPA, Chapter 14. |
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Treatment for Arsenical Poisoning | ||||
See: Recognition and Management of Pesticide Poisoning, 5th edition, U.S. EPA, Chapter 14, page 129. | ||||
Toxicity Information for MSMA |
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Summary Toxicity Information | ||||||
| PAN Bad Actor Chemical 1 | Acute Toxicity 2 | Carcinogen | Cholinesterase Inhibitor | Ground Water Contaminant | Developmental or Reproductive Toxin | Endocrine Disruptor |
|---|---|---|---|---|---|---|
| Slight | No | Potential | ||||
| Indicates high toxicity in the given toxicological category. | Indicates no available weight-of-the-evidence summary assessment. For additional information on toxicity from scientific journals or registration documents, see the "Additional Resources for Toxicity " section of the chemical detail page. | ||
| 1. PAN Bad Actors are chemicals that are one or more of the following: highly acutely toxic, cholinesterase inhibitor, known/probable carcinogen, known groundwater pollutant or known reproductive or developmental toxicant. NOTE! Because there are no authoritative lists of Endocrine Disrupting (ED) chemicals, EDs are not yet considered PAN Bad Actor chemicals. | |||
| 2. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. | |||
Additional Resources about the Toxicity of this Chemical |
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See the Global Pesticide Resources page for many additional links. | |
Detailed Toxicity Information |
This Chemical |
Parent Chemical |
Acute Toxicity 2 |
MSMA |
Cacodylic acid
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WHO Acute Hazard TRI Acute Hazard Material Safety Data Sheets Acute rating from U.S. EPA product label U.S. NTP Acute Toxicity Studies
View StudiesCholinesterase Inhibitor |
Not Listed Not Listed Not Available No Consensus Value Slightly Toxic No |
III, Slightly Hazardous Not Listed Not Available No Consensus Value No NTP Studies No |
| 2. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. | ||
Cancer Information |
MSMA |
Cacodylic acid
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IARC Carcinogens U.S. NTP Carcinogens California Prop 65 Known Carcinogens U.S. EPA Carcinogens TRI Carcinogen |
1, Known Not Listed Not Listed Not Likely Not Listed |
1, Known Not Listed Yes B2, Probable Not Listed |
Endocrine Disruption |
MSMA |
Cacodylic acid
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Illinois EPA list Keith list Colborn list Benbrook list Danish Inert list EU list |
Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed |
Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed |
Reproductive and Developmental Toxicity |
MSMA |
Cacodylic acid
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CA Prop 65 Developmental Toxin U.S. TRI Developmental Toxin CA Prop 65 Female Reproductive Toxin CA Prop 65 Male Reproductive Toxin U.S. TRI Reproductive Toxin |
Not Listed Not Listed Not Listed Not Listed Not Listed |
Not Listed Not Listed Not Listed Not Listed Not Listed |
Chemicals of Special Concern |
MSMA |
Cacodylic acid
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| PAN
Bad Actors PAN Dirty Dozen list |
Yes Not Listed |
Yes Not Listed |
Water Pollution Potential and Criteria for MSMA |
Water Pollution Potential |
This Chemical |
Parent Chemical |
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| MSMA |
Cacodylic acid
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| PAN Ground Water Contaminant Rating | Potential | Potential | ||
Physical Property Data Related to Water Contamination Potential | ||||
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Water Solubility
(Avg, mg/L)
Adsorption Coefficient (Koc) Hydrolysis Half-life (Avg, Days) Aerobic Soil Half-life (Avg, Days) Anaerobic Soil Half-life (Avg, Days) |
1,040,000
1,680 35.0 269.0 - |
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Sorry, no water quality standards or criteria have been established for this chemical by the U.S. or Canadian governments; however, there may be criteria established for related chemicals. |
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Regulatory Information for MSMA |
International Regulatory Status |
This Chemical |
Parent Chemical |
| Registration in Selected Countries | MSMA |
Cacodylic acid |
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UNEP Persistent Organic Pollutant (POP) UNEP Prior Informed Consent Chemical (PIC) WHO Obsolete Pesticide |
Not Listed Not Listed Not Listed |
Not Listed Not Listed Not Listed |
U.S. and California Regulatory Status |
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U.S. EPA Registered U.S. EPA Hazardous Air Pollutant U.S. EPA Minimum Risk Pesticide (25b list) CA Registered CA Groundwater Contaminant CA Toxic Air Contaminant |
Yes Not Listed No Yes Not Listed Not Listed |
No Not Listed No Yes Not Listed Not Listed |
Maximum Tolerance and Residue Levels |
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Codex Alimentarius (UN FAO Maximum Residue Limits) U.S. Maximum Tolerance Levels European Union Maximum Residue Levels |
Go
to web site Go to web site Go to web site |
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Ecotoxicity for MSMA |
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Aquatic Ecotoxicity |
All Toxic Effects for Organism Group |
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| Organism Group | Effects Noted |
|---|---|
| Mortality | |
| Accumulation, Development, Mortality, Population | |
| Accumulation, Mortality | |
| Accumulation, Biochemistry, Genetics, Mortality, Physiology | |
| Accumulation, Behavior, Intoxication, Population | |
| Accumulation, Biochemistry, Physiology, Population | |
| Accumulation, Intoxication, Mortality | |
Summary of Acute Toxicity for Organism Group |
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| Organism Group | Average Acute Toxicity | Acute Toxicity Range |
|---|---|---|
| Not Acutely Toxic | Not Acutely Toxic to Slightly Toxic | |
| Not Acutely Toxic | Not Acutely Toxic to Slightly Toxic | |
| Slightly Toxic | Not Acutely Toxic to Slightly Toxic | |
Terrestrial Ecotoxicity |
We are seeking funding to incorporate terrestrial ecotoxicity data analogous to the aquatic ecotoxicity data in the space above. Watch this space! |
Related Chemicals for MSMA |
| CAS Number | Relation | Reason | Chemical Name | Chem Detail | Registration | Symptoms | California Use | Chem Use Type | U.S. EPA Reg | PAN Bad Actor |
|---|---|---|---|---|---|---|---|---|---|---|
| 75-60-5 | Parent | P | Cacodylic acid | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 5902-95-4 | Related | 3 | Calcium acid methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 6423-72-9 | Related | 3 | Calcium methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 126-94-3 | Related | 3 | Calcium propanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 53404-47-0 | Related | 3 | Dodecyl ammonium methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 144-21-8 | Related | 3 | DSMA | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 124-58-3 | Related | 3 | Methane arsonic acid (MAA) | View |
View |
View |
View |
Herbicide | No | Yes |
| 2321-53-1 | Related | 3 | Monoammonium methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 2163-80-6 | Related | 3 | MSMA | View |
View |
View |
View |
Herbicide, Defoliant | Yes | Yes |
| 6379-37-9 | Related | 3 | Octylammonium methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 124-65-2 | Related | 3 | Sodium cacodylate | View |
View |
View |
View |
Herbicide, Defoliant, Rodenticide | No | Yes |
| 69484-14-6 | Related | 3 | Triethanolamine cacodylate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| 5902-97-6 | Related | 3 | Triethanolamine methanearsonate | View |
View |
View |
View |
Herbicide, Defoliant | No | Yes |
| Working with the Information on this Page | |
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Click on underlined terms for definitions or go to the Pesticide Tutorial overview page. Any underlined term with a book icon * Data marked with an asterisk indicates that this chemical is not explicitly listed on the corresponding list. Instead, it belongs to a group of chemicals that IS designated on the list. For example, if an agency assigns a classification of reproductive toxicant
to "mercury compounds", that classification is applied to all mercury compounds in the PAN Pesticide database, which are then marked with an asterisk. | |