PAN Pesticides Database - Chemicals

Cupric acetoarsenite - Identification, toxicity, use, water pollution potential, ecological toxicity and regulatory information

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Identifying information, including synonyms, ID numbers, use type, chemical classification, a link to a list of all products containing this chemical and a list of the top crops this pesticide is used on in California.
Signs and symptoms of poisoning, first aid, and links to treatment information for this chemical.
Link to information on toxicity to humans, including carcinogenicity, reproductive and developmental toxicity, neurotoxicity, and acute toxicity.
Links to world-wide registration status as well as regulatory information for the U.S. and California.
Water quality standards and physical properties affecting water contamination potential.
Toxicity to aquatic organisms.
List of chemicals in the same family, including breakdown products, salts, esters, isomers, and other derivatives.
 

Chemical Identification and Use for Cupric acetoarsenite

Basic Identification Information About This Chemical
Chemical Name: Cupric acetoarsenite
CAS Number: 12002-03-8
U.S. EPA PC Code: 022601
CA DPR Chem Code: 2485 (Cupric acetoarsenite. Two chem codes for the same compound.)
460 (Paris green. Two chem codes for the same compound.)
Molecular Weight: 1013.78
Use Type: Wood Preservative
Chem Class: Heavy metal , Inorganic-Arsenic , Inorganic-Copper
View Related Chemicals
 
Additional Resources About This Chemical Class and Use Type
 
Other Names for this Chemical
About Chemical Synonyms
(US EPA PC Code ) , 022601 (US EPA PC Code Text ) , 12002-03-8 (CAS number) , 12002038 , 12002038 (CAS number without hyphens) , 2485 (CA DPR Chem Code) (Cupric acetoarsenite. Two chem codes for the same compound.)) , 460 (CA DPR Chem Code) (Cupric acetoarsenite. Two chem codes for the same compound.)) , Acetoarsenito De Cobre , Bis(acetato)hexametaarsenitotetracopper , Copper acetoarsenite , Cupric acetoarsenite , CUPRIC ACETOARSENITE (CA DPR Chem Code Text (Cupric acetoarsenite. Two chem codes for the same compound.)) , Cupricacetoarsenite , Emerald green , French green , Mitis green , Paris green , PARIS GREEN (CA DPR Chem Code Text (Cupric acetoarsenite. Two chem codes for the same compound.)) , Schweinfurt green
 
Products Containing This Chemical
Current and historic U.S. registered products
View U.S. Products All Products Currently Registered Products
 

Signs and Symptoms of Cupric acetoarsenite Poisoning

NOTE! There may be other diseases and chemicals that have similar symptoms.

If you have a poisoning emergency in the United States call 1-800-222-1222.
If the victim has collapsed or is unconscious, call 911.

Cupric acetoarsenite is a Arsenical compound.

Report a Poisoning

Symptoms of Poisoning with Arsenical Compounds
Find Products Containing this Chemical

- Garlic odor of breath and feces, metallic taste in mouth.
- Adverse GI effects predominate with vomiting, abdominal pain and rice-water or bloody diarrhea. GI effects may also include inflammation, vesicle formation and eventual sloughing of the mucosa in the mouth, pharynx and esophagus.
- Central nervous system effects are common: headache, dizziness, drowsiness and confusion.
- Symptoms may progress to include muscle weakness and spasms, hypothermia, lethargy, delirium, coma and convulsions.
- Renal injury is manifest as proteinuria, hematuria, glycosuria, oliguria, casts in the urine and in severe poisoning cases, acute tubular necrosis.
- Cardiovascular effects include shock, cyanosis and cardiac arrhythmia.
- Liver damage may be manifested by elevated liver enzymes and jaundice.
- Injury to blood-forming tissues may cause anemia, leucopenia and thrombocytopenia.
Chronic exposure may lead to:
- Muscle weakness, fatigue, anorexia, weight loss.
- Hyperpigmentation, hyperkeratosis.
- Peripheral neuropathy, paresthesia, paresis and ataxia.
- Inability to coordinate voluntary muscular movements.
- Subcutaneous edema in face, eyelids, and ankles.
- Stomatitis, white striations across the nails (Mees lines) and sometimes loss of nails or hair.
- Liver toxicity as indicated by hepatomegaly, jaundice, cirrhosis.
- Renal toxicity leading to oliguria, proteinuria, and hematuria.
- EKG abnormalities and peripheral vascular disease.
- Hematologic abnormalities.
- Cancer.

Source for Group Symptoms: Recognition and Management of Pesticide Poisoning, 5th edition, U.S. EPA, Chapter 14.

Treatment for Arsenical Poisoning

See: Recognition and Management of Pesticide Poisoning, 5th edition, U.S. EPA, Chapter 14, page 129.

 
Symptoms of Cupric acetoarsenite Exposure

- Eye and upper respiratory tract irritation; corrosive to skin; itching, burning, watering of eyes. Visual impairment, dislike of bright light, night blindness, black dots in front of the eyes, and blurring of vision.
- A highly characteristic dermatitis confined to the scrotum, inguinal area, and nasolabial folds may follow moderate occupational exposure. The lesions begin with erythema, frequently become eczematous and weeping, and may start to heal with ... black scab. A sensitization reaction may be involved.
- In less acute cases, hyperkeratosis, hyperhidrosis, or melanosis may occur. ... The hyperpigmentation is most marked on surfaces exposed to light.

Source for Symptoms: Hazardous Substances Data Bank, National Library of Medicine, Bethesda, MD. February 2003. (HSDB)

First Aid for Cupric acetoarsenite Poisoning

For Inhalation
- Move victim to fresh air. Call 911 or emergency medical service. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.
For Skin
- Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.
For Eyes
- In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
For Ingestion
- No information provided

Source for First Aid: Hazardous Substances Data Bank, National Library of Medicine, Bethesda, MD. February 2003. ()

Treatment for Cupric acetoarsenite Poisoning

See: Recognition and Management of Pesticide Poisoning, 5th edition, U.S. EPA (EPA R&M)

 
 

Toxicity Information for Cupric acetoarsenite

  Note: Information for many chemicals is incomplete and may not be fully representative of effects on humans. Why?

Summary Toxicity Information

PAN Bad Actor
Chemical
1
Acute
Toxicity
2
Carcinogen Cholinesterase
Inhibitor
Ground
Water Contaminant
Developmental or
Reproductive Toxin
Endocrine
Disruptor
No
Suspected
 
Indicates high toxicity in the given toxicological category. Indicates no available weight-of-the-evidence summary assessment. For additional information on toxicity from scientific journals or registration documents, see the "Additional Resources for Toxicity " section of the chemical detail page.
1. PAN Bad Actors are chemicals that are one or more of the following: highly acutely toxic, cholinesterase inhibitor, known/probable carcinogen, known groundwater pollutant or known reproductive or developmental toxicant. NOTE! Because there are no authoritative lists of Endocrine Disrupting (ED) chemicals, EDs are not yet considered PAN Bad Actor chemicals.
2. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above.

Detailed Toxicity Information

This Chemical
Parent Chemical 
Acute Toxicity 2
Cupric acetoarsenite Arsenic
WHO Acute Hazard
TRI Acute Hazard
Material Safety Data Sheets
Acute rating from U.S. EPA product label
U.S. NTP Acute Toxicity Studies
      View Studies
Cholinesterase Inhibitor
Ib, Highly Hazardous
Not Listed
Not Available
Highly Toxic
Slightly to Highly Toxic

No
Not Listed
Not Listed
Not Available
No Consensus Value
No NTP Studies

No
2. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above.
 
Cancer Information
Cupric acetoarsenite Arsenic
IARC Carcinogens
U.S. NTP Carcinogens
California Prop 65 Known Carcinogens
U.S. EPA Carcinogens
TRI Carcinogen
1, Known
Known
Yes
Not Listed
Not Listed
Not Listed
Known
Yes
Not Listed
Not Listed
 
Endocrine Disruption
Cupric acetoarsenite Arsenic
Illinois EPA list
Keith list
Colborn list
Benbrook list
Danish Inert list
EU list
Not Listed
Yes
Yes
Not Listed
Not listed
Not listed
Not Listed
Yes
Yes
Not Listed
Not listed
Not listed
 
Reproductive and Developmental Toxicity
Cupric acetoarsenite Arsenic
CA Prop 65 Developmental Toxin
U.S. TRI Developmental Toxin
CA Prop 65 Female Reproductive Toxin
CA Prop 65 Male Reproductive Toxin
U.S. TRI Reproductive Toxin
Yes
Not Listed
Not Listed
Not Listed
Not Listed
Yes
Not Listed
Not Listed
Not Listed
Not Listed
 
Chemicals of Special Concern
Cupric acetoarsenite Arsenic
PAN Bad Actors
PAN Dirty Dozen list
Yes
Not Listed
Yes
Not Listed
 

Water Pollution Potential and Criteria for Cupric acetoarsenite

Water Pollution Potential

This Chemical
Parent Chemical
  Cupric acetoarsenite Arsenic
PAN Ground Water Contaminant Rating Insufficient Data Insufficient Data
 

Sorry, no water quality standards or criteria have been established for this chemical by the U.S. or Canadian governments; however, there may be criteria established for related chemicals.

 

Regulatory Information for Cupric acetoarsenite

International Regulatory Status

This Chemical
Parent Chemical 
 
UNEP Persistent Organic Pollutant (POP)
UNEP Prior Informed Consent Chemical (PIC)
WHO Obsolete Pesticide
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
 

U.S. and California Regulatory Status

U.S. EPA Registered
U.S. EPA Hazardous Air Pollutant
U.S. EPA Minimum Risk Pesticide (25b list)

CA Registered
CA Groundwater Contaminant
CA Toxic Air Contaminant
No
Yes
No

No
Not Listed
HAPTAC, Indus
No
Yes
No

No
Not Listed
HAPTAC, Indus
 

Maximum Tolerance and Residue Levels

Codex Alimentarius
   (UN FAO Maximum Residue Limits)
U.S. Maximum Tolerance Levels
European Union Maximum Residue Levels
Go to web site

Go to web site

Go to web site
 

Ecotoxicity for Cupric acetoarsenite

Note! Information for many chemicals is incomplete and may not be fully representative of effects on the environment. Why? Click on underlined terms for definitions and additional information.

Aquatic Ecotoxicity

All Toxic Effects for Organism Group
Organism Group Effects Noted
Fish Mortality
View All Aquatic Ecotoxicity Studies and References
 
Summary of Acute Toxicity for Organism Group
Organism Group Average Acute Toxicity Acute Toxicity Range
Fish Slightly Toxic Slight Toxicity
View All Acute Summaries
 

Terrestrial Ecotoxicity

Summary of Acute Toxicity for Organism Group

Sorry, no honeybee acute toxicity data available for this chemical. Try related chemicals.

Note: Population-level effects on honeybees may occur even if a pesticide has low acute toxicity. For example, certain pesticides interfere with honeybee reproduction, ability to navigate, or temperature regulation, any of which can have an effect on long-term survival of honeybee colonies. The neonicotinoids, pyrethroids and keto-enol pesticides are some types of pesticides causing one or more of these effects.
Honeybee Chronic Toxicity

Sorry, no honeybee chronic toxicity data available for this chemical. Try related chemicals.

Related Chemicals for Cupric acetoarsenite

CAS Number Relation Reason Chemical Name Chem Detail Symptoms California Use Chem Use Type U.S. EPA Reg PAN Bad Actor
7440-38-2 Parent P Arsenic View View View Herbicide, Insecticide, Rodenticide No Yes
7784-44-3, 13462-93-6 Related 3 Ammonium arsenate View View View Herbicide, Insecticide, Rodenticide No Yes
Related 1 Ammonium iron methyl arsonate View View View No Not Listed
Related Arsenic (inorganic oxides) View View View Industrial chemical No Yes
7778-39-4 Related 3 Arsenic acid View View View Herbicide, Insecticide, Rodenticide Yes Yes
xx7440-38-2 Related 3 Arsenic and arsenic compounds View View View Herbicide, Rodenticide No Yes
x7440-38-2 Related 3 Arsenic compounds, inorganic View View View Herbicide, Rodenticide, Electronics production, Battery component, Building mate No Yes
56320-22-0 Related 3 Arsenic disulfide View View View Herbicide, Insecticide, Rodenticide No Yes
Related P Arsenic in drinking-water View View View No Yes
1303-28-2 Related 3 Arsenic pentoxide View View View Fungicide, Insecticide, Rodenticide, Herbicide Yes Yes
12612-21-4, 12344-68-2 Related 3 Arsenic sulfide View View View Herbicide, Insecticide, Rodenticide No Yes
1327-53-3 Related 3 Arsenic trioxide View View View Herbicide, Insecticide, Rodenticide No Yes
1303-33-9, 1303-34-0, 12044-79-0 Related 3 Arsenic trisulfide View View View Herbicide, Insecticide, Rodenticide No Yes
98-50-0 Related 3 Arsonic acid, (4-aminophenyl)- View View View No Yes
58829-95-1, 13462-94-7, 53404-17-4 Related 3 Arsonic acid, ammonium salt View View View Herbicide, Insecticide, Wood Preservative No Yes
16102-92-4 Related 3 Basic copper arsenate View View View Herbicide, Insecticide, Rodenticide No Yes
7778-44-1 Related 3 Calcium arsenate View View View Herbicide, Insecticide, Rodenticide, Molluscicide No Yes
53404-59-4 Related 3 Calcium arsenite View View View Herbicide, Insecticide, Rodenticide No Yes
10290-12-7 Related 3 Copper arsenite View View View Herbicide, Insecticide, Rodenticide No Yes
12002-03-8 Related 3 Cupric acetoarsenite View View View Wood Preservative No Yes
10103-50-1 Related 3 Magnesium arsenate View View View Herbicide, Insecticide, Rodenticide No Yes
7784-38-5 Related 3 Manganese arsenate View View View Herbicide, Insecticide, Rodenticide No Yes
10124-50-2, 13464-35-2 Related 3 Potassium arsenite View View View Herbicide, Insecticide, Rodenticide No Yes
17029-22-0 Related 3 Potassium hexafluoroarsenate View View View No Yes
13464-38-5 Related 3 Sodium arsenate View View View Herbicide, Insecticide, Rodenticide No Yes
7784-46-5 Related 3 Sodium arsenite View View View Herbicide, Insecticide, Rodenticide, Fungicide No Yes
13464-42-1 Related 3 Sodium pyroarsenate View View View Wood Preservative, Fungicide No Yes
17367-56-5, 16486-45-6, 26273-99-4 Related 3 Sodium thioarsenate View View View No Yes
 
Working with the Information on this Page

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